Molecular Parameters - Transition Metal Compounds
| Molecular Formula | Name | Structure | Bond Length (Å) | Bond Angle (°) | Symmetry |
|---|---|---|---|---|---|
| VCl4 | vanadium tetrachloride | V-Cl 2.03 ± 0.02 | Td | ||
| [VO4]3- | in BiVO4 | V-O 1.86 (avg.) | Td | ||
| [CrO4]2- |  in (NH4)2CrO4 |
a = b = 1.98 c = d = 1.60 | ab = 105 cd = 138 ac = bc = ad = bd = 103 | C2v | |
| [Cr2O7]2- |  in (NH4)2Cr2O7 |
a = 1.91 b = c = d = 1.63 | a1a2 = 115 | C2 | |
| [MoO4]2-(s) | in Ag2MoO4 | Mo-O = 1.83 | Td | ||
| [WO4]2-(s) | W-O = 1.81 in BaWO4, 1.75 in CaWO4, 1.78 in PbWO4, 1.79 in SrWO4 | Td | |||
| [MnO4]- | in KMnO4 | Mn-O 1.59 | Td | ||
| TiCl4 | titanium tetrachloride | Ti-Cl 2.18 ± 0.04 | Td |
ass. = assumed parameter
( ) = preliminary results
(s) = in crystalline state
Reference: Tables of Interatomic Distances and Configuration in Molecules and Ions, L.E. Sutton, ed., London: The Chemical Society, 1958.